Abstract

1. 1. It is to be expected that the hysteresis of contact angles on polystyrene would be the effect of a number of simultaneous causes. Whatever the interpretation, the differences in the observed angles found with surfaces that had been formed in different ways point to structural differences among the samples; and the existence of structural differences would indicate that all the surfaces depart appreciably from ideality, e.g., from ideal flatness, rigidity, and homogeneity. 2. 2. We have shown that effects due to film pressure, πe, would be in the opposite direction from those observed in hysteresis. Hence film pressure is not responsible for contact angle hysteresis.

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