Abstract
The Bürgi–Dunitz angle is one of those memes that most students of organic chemistry remember.&nbsp;It hypothesizes the geometry of attack of a&nbsp;nucleophile&nbsp;on a&nbsp;trigonal&nbsp;unsaturated (sp <sup> 2 </sup> ) carbon in a&nbsp;molecule&nbsp;such as&nbsp;ketone, aldehyde,&nbsp;ester, and&nbsp;amide&nbsp;carbonyl.
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