Abstract
The photoacoustic spectrum (PAS) was measured in the near IR region (1000 to 2600 nm) for organic compounds (C 6H 6, C 6D 6, C 7H 8, and C 6H 12) and organometallic compounds (Cp 2Fe, Cp 2Fe 2(CO) 4, Cp 4Fe 4(CO) 4, Cp 4Fe 4S 4, C 6H 6Cr(CO) 3, CpCo(C 4Ph 4) and CpCo(CO) 2). Band assignments were made by comparison to the infrared spectra. The bands were assigned as the CH overtone stretch and combinations of CH and other IR fundamentals. These bands provide fingerprint spectra for these compounds.
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