Abstract
Abstract Morita–Baylis–Hillman acetates undergo smooth allylic nucleophilic substitution (S N 2′) with tosylmethyl isocyanide (TosMIC) in the presence of a catalytic amount of BF 3 ·OEt 2 under mild conditions to furnish trisubstituted olefins in high yields with ( E )-stereoselectivity.
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