Abstract

Abstract Adsorption isotherms for four kinds of polyvinyl pyrrolidone (PVP), having different molecular weights, on the sol particles and the powder of silver iodide at 25°C were obtained. Further, the adsorption of PVP on the sol particles was investigated by means of the electrophoresis method. All of the PVP materials give approximate adsorption isotherms of the Langmuir type, at least up to the PVP concentration of 0.4 g/l At higher concentrations, the amounts of PVP adsorbed gradually increase with the increase in the PVP concentration. The effect of the molecular weight on the PVP adsorption is not observed except for the lowest-molecular-weight material, which displays a lower adsorption. The tendency for the ζ-potential of the sol particles to increase with an increase in the PVP concentration almost coincides with that of the amount of PVP adsorbed.

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