The absorption spectra of benzene derivatives in the vacuum ultraviolet.

Abstract

New photographs of the far ultra-violet spectrum of benzene are presented. The absorption from 2000 to 1800A ( λ max , c . 1980A) is regarded not as a part of the much stronger absorp­tion of peak at 1790A but as due to a separate transition. Sharp bands lying at 1790A represent the first member of a previously reported Rydberg series. The spectra of toluene, xylene, monochloro-and o -dichlorobenzene, bromobenzene, iodoben-zene and pyridine are briefly described, and the shifts relative to benzene are discussed. Two Rydberg series were observed for toluene, converging to a first ionization potential of 8.77 ± 0.05 V.