Abstract

The absence of linearity is proved for the …OGeOGe… bonds in polymeric germanium phthalocyanine H(OGePc) i OH by comparing the electronic spectra with the kinetics of dissociation in concentrated H 2SO 4. It was found that intermolecular H-bond is present in the compounds (OH) 2GePc and H(OGePc) i OH. It is shown that (OH) 2GePc polymerization through a central atom increases the kinetic stability of the compound. A difference was found in the dissociation mechanisms of phthalocyanines of silicon and germanium.

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