Abstract

The 55Mn nuclear magnetic resonance spectra of alkyl- and acryl-manganese pentacarbonyls and related compounds in solution in tetrahydrofuran have been measured at a frequency of 14·858 Mc./s. The observed chemical shifts cover a range of 1020–2780 p.p.m. to the high field of an aqueous solution of potassium permanganate, the line-widths are in general large owing to quadrupole relaxation. The nuclear magnetic resonance data are interpreted in terms of the bonding in these compounds.

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