The δ13C record of Maastrichtian-Paleocene oil shales from Jordan – Stratigraphic and environmental implications for an epicontinental setting

Abstract

Organic matter (OM) rich marls were deposited in several intrashelf basins in Jordan (e.g. Yarmouk Basin, Lajjun Basin, Azraq-Hamza Basin, Jafr Basin, Eshidiyya Basin) on the southeastern Tethyan margin during the Maastrichtian to middle Eocene. Factors like surface water productivity fueled by upwelling and sea level changes affected their deposition. Potential effects of climatic changes have not been determined yet.We present the first stable carbon and oxygen isotope records of Maastrichtian-Danian oil shales from the Azraq-Hamza and Jafr Basins in south- and central-east Jordan. The δ13Ccarb curves were time-calibrated based on calcareous nannofossil biostratigraphy. Eight notable excursions were identified in the Jordanian Maastrichtian sections. These were correlated with the documented Maastrichtian δ13Ccarb events in the (sub) tropical sections of Italy and the western Pacific: the Campanian-Maastrichtian boundary Events 4 and 5 (CMBE-4, CMBE-5), the Middle Maastrichtian Events 1 to 3 (MME-1 to MME-3) and the Cretaceous-Paleogene boundary Events 1 to 3 (KPgE-1 to KPgE-3). Signs of the Latest Danian Event (LDE) were recognized as well. Total organic carbon (TOC) data exhibit a complex relationship with the δ13Ccarb proxy record. The δ13Ccarb signals are repeatedly dampened due to the OM oxidation and subsequent 12C release. The effect of short term climate changes is observed, but is not always straight forward. Long term climate changes had indirect effects on bottom water oxygenation and OM preservation via sea level changes. The δ18Ocarb data from both sections reveal minor temperature changes in the Maastrichtian. Slight warming is observed in the MME interval. A potential increase of the paleotemperature is reported from the Azraq-Hamza section occurring in the latest Maastrichtian to earliest Danian.