Abstract
Solvent resistant nanofiltration (SRNF) is now a powerful tool for addressing environmental issues. Hence, we report the fabrication of a thin film composite (TFC) membrane comprised of a novel HDPE support, a polydopamine (PDA)/Tannic acid-Fe(III) interlayer and a polyamide (PA) skin layer. In this respect, high density polyethylene (HDPE)-polystyrene (PS)-styrene-ethylene-butylene-styrene (SEBS) blends were formed with different compositions by mixing via a Brabender machine and making films by using a hot press instrument. Next, a solvent extraction technique was employed for extracting the dispersed phase and making the HDPE membranes. The support membrane with optimum properties was coated with a PDA interlayer. A tannic acid-Fe(III) interlayer was also formed on the as-prepared PDA layer so that the hydrophilicity of the support surface was enhanced to form a defect-free PA layer. The modified support was utilized for the fabrication of the PA top layer by using m-phenylene diamine (MPD) and trimesoyl chloride (TMC) monomers. The prepared TFC membrane provided a significant dye rejection ability (99.9% Direct Yellow, 99.7% Methyl Green, 99.2% Rhodamine B, and 96.1% Methyl Orange), extraordinary solvent resistance ability in harsh solvents, and good methanol (MeOH) Flux (2.25 L/m2.h.bar) in SRNF applications. The skin-substrate adhesion strength of the top layer was also evaluated by a back-ward flush operation. It was demonstrated that the interlayer and the skin layer had an excellent adhesion with the support membrane.
Published Version
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