Abstract

HighlightsEvaporation and solution two-step hybrid process are used to fabricate conformal growth of perovskite film on textured silicon substrates.F-PMAI additive enlarged the perovskite grains, induced the (111) preferred orientation and passivated interface defects.We obtained a champion efficiency of 30.05% for a monolithic perovskite/silicon tandem solar cell based on a silicon thin film tunneling junction.

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