Abstract
Polystyrene and polystyrene-b-polyvinylacetate have been prepared in presence of either tetrathiophosphoric acidtri(1-phenylethyl) ester 1 or 1-phenylethyl-diphenylphosphinodithioate 2 under radical conditions. From kinetic studies performed with or without 1 or 2, it was shown that the polymerization presents the criteria of living/controlled polymerization.
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