Abstract
The CuI atom of the title complex, [Cu(C7H8N2S)4]Cl, is located on a \overline 4 inversion axis and has distorted tetrahedral coordination geometry, formed by four phenylthiourea S atoms. Within the phenylthiourea ligands, the C—N(imino) bonds [1.341 (2) A] are significantly longer than the C—N(amino) bonds [1.316 (3) A]. The Cl− anion is located on another \overline 4 inversion axis and links with four complex cations via N—H⋯Cl hydrogen bonding.
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