Abstract
In the centrosymmetric title compound, [Ho2(C10H11O4)6(C12H8N2)2], the HoIII atom is nine-coordinated by seven O atoms from the 3,4-dimethoxyphenylacetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) molecule. The L ligands are coordinated to the HoIII ions in three modes: chelating, bridging and bridging–tridentate. Intramolecular C—H⋯O interactions occur. The crystal packing is stabilized by intermolecular C—H⋯O interactions and weak aromatic π–π interactions between phen molecules and the aromatic rings of the L ligands [centroid–centroid distance = 3.821 (2) Å].
Highlights
In the centrosymmetric title compound, [Ho2(C10H11O4)6(C12H8N2)2], the HoIII atom is nine-coordinated by seven O atoms from the 3,4-dimethoxyphenylacetate (L) anions and two N atoms from a 1,10-phenanthroline molecule
L ligands are coordinated to the HoIII ions in three modes: chelating, bridging and bridging–tridentate
The crystal packing is stabilized by intermolecular C—H O interactions and weak aromatic
Summary
Normal University Xingzhi College, Jinhua, Zhejiang 321004, People’s Republic of. R factor = 0.033; wR factor = 0.068; data-to-parameter ratio = 17.4. In the centrosymmetric title compound, [Ho2(C10H11O4)6(C12H8N2)2], the HoIII atom is nine-coordinated by seven O atoms from the 3,4-dimethoxyphenylacetate (L) anions and two N atoms from a 1,10-phenanthroline (phen) molecule. The. L ligands are coordinated to the HoIII ions in three modes: chelating, bridging and bridging–tridentate. The crystal packing is stabilized by intermolecular C—H O interactions and weak aromatic. – interactions between phen molecules and the aromatic rings of the L ligands [centroid–centroid distance =
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More From: Acta Crystallographica Section E Structure Reports Online
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