Abstract
The title compound, [Fe(C10H8N2)2(H2O)4](C7H3NO4)·4H2O, prepared by hydrothermal synthesis, contains isolated tetraaquabis(4,4′-bipyridine)iron(II) cations, comprising two 4,4′-bipyridine molecules bound to FeII in a trans manner. The cations lie in layers, with pyridine-2,6-dicarboxylate dianions and water molecules forming an extensive hydrogen-bond network between them. The cations exhibit noncrystallographic inversion symmetry. The crystal was a partial inversion twin.
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