Abstract
The title compound, (C4H12NO3)[ReO4], contains two cations and two anions in the asymmetric unit, related by a non-crystallographic centre of symmetry. The crystal structure is stabilized by an extensive hydrogen-bonding network with the formation of puckered layers perpendicular to [001]. In the tris(hydroxymethyl)ammonium cations, intramolecular O—H⋯O hydrogen bonds are present with the formation of an S 1 1(6) graph-set motif. The crystal structure is further consolidated by N—H⋯O hydrogen bonds.
Highlights
The title compound, (C4H12NO3)[ReO4], contains two cations and two anions in the asymmetric unit, related by a noncrystallographic centre of symmetry
The crystal structure is further consolidated by N—H O hydrogen bonds
Symmetry codes: (i) x−1/2, −y+1, z; (ii) x, y−1, z; (iii) x+1/2, −y, z; (iv) x, y+1, z
Summary
Extensive hydrogen-bonding network and an unusual cation conformation in [tris(hydroxymethyl)methyl]ammonium tetraoxidorhenate(VII). Faculty of Chemistry, University of Wrocław, 14 Joliot-Curie St, 50-383 Wrocław, Poland. R factor = 0.020; wR factor = 0.034; data-to-parameter ratio = 24.0. The title compound, (C4H12NO3)[ReO4], contains two cations and two anions in the asymmetric unit, related by a noncrystallographic centre of symmetry. The crystal structure is stabilized by an extensive hydrogen-bonding network with the formation of puckered layers perpendicular to [001]. The crystal structure is further consolidated by N—H O hydrogen bonds
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
