Abstract
In the anion of the title compound, (C16H36N)[Cd(C5H8NS2)(C12H27O3SSi)I], the Cd atom is four-coordinated by S,S′-chelating dithiocarbamate, S–donating silanethiolate and iodide ligands in a distorted tetrahedral environment . Intermolecular C—H⋯ S and C—H⋯I interactions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35.
Highlights
In the anion of the title compound, (C16H36N)[Cd(C5H8NS2)(C12H27O3SSi)I], the Cd atom is four-coordinated by S,S0 chelating dithiocarbamate, S–donating silanethiolate and iodide ligands in a distorted tetrahedral environment
Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35
In the present paper we describe the product of a reaction between cadmium tri-tert-butoxysilanethiolate, ammonium 1pyrrolidinylcarbodithioate and tetraethylammonium iodide carried out in toluene/propanol-2 mixture
Summary
Key indicators: single-crystal X-ray study; T = 120 K; mean (C–C) = 0.007 Å; disorder in main residue; R factor = 0.039; wR factor = 0.088; data-to-parameter ratio = 20.4. In the anion of the title compound, (C16H36N)[Cd(C5H8NS2)(C12H27O3SSi)I], the Cd atom is four-coordinated by S,S0 chelating dithiocarbamate, S–donating silanethiolate and iodide ligands in a distorted tetrahedral environment. Intermolecular C—H S and C—H I interactions between cations and anions are present. Two C atoms of a tert-butyl group are disordered over two positions; the site occupancies are ca 0.65 and 0.35
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