Abstract
The title complex, [Nd2(C8H7O3)6(C10H8N2)2(H2O)2]·H2O, contains two Nd atoms, six 4-hydroxyphenylacetate (hpaa) anions, two 4,4′-bipyridine molecules (bipy) and two water molecules; an additional water molecule of solvation is also present in the crystal structure. Each of the NdIII ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water molecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the NdIII ions in the bridging and bridging tridentate modes. Extensive O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonding stabilizes the crystal structure.
Highlights
The title complex, [Nd2(C8H7O3)6(C10H8N2)2(H2O)2]H2O, contains two Nd atoms, six 4-hydroxyphenylacetate anions, two 4,40 -bipyridine molecules and two water molecules; an additional water molecule of solvation is present in the crystal structure
Each of the NdIII ions is ninecoordinated by seven O atoms from four hpaa ligands, an N
The hpaa ligands are coordinated to the NdIII ions in the bridging and bridging tridentate modes
Summary
College of Chemistry and Life Sciences, Zhejiang Normal University and, Zhejiang. R factor = 0.021; wR factor = 0.053; data-to-parameter ratio = 12.8. The title complex, [Nd2(C8H7O3)6(C10H8N2)2(H2O)2]H2O, contains two Nd atoms, six 4-hydroxyphenylacetate (hpaa) anions, two 4,40 -bipyridine molecules (bipy) and two water molecules; an additional water molecule of solvation is present in the crystal structure. Each of the NdIII ions is ninecoordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water molecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the NdIII ions in the bridging and bridging tridentate modes. Extensive O—H O, O—H N and C—H O hydrogen bonding stabilizes the crystal structure
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More From: Acta crystallographica. Section E, Structure reports online
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