Testing of gadolinium oxy-sulphide phosphors for use in CCD-based X-ray detectors for macromolecular crystallography

Abstract

The resolution and detective quantum efficiency of CCD-based detectors used for X-ray diffraction is primarily affected by the layer of phosphor that converts incident X-ray photons into visible photons. The optimum thickness of this phosphor layer is strongly dependent on the fraction of absorbed incident X-ray photons and required spatial resolution. A range of terbium doped gadolinium oxy-sulphide (Gd 2O 2S : Tb) phosphor samples, provided by Applied Scintillation Technologies, have been evaluated for spatial resolution, light output and uniformity. The phosphor samples varied in coating weight (10–25 mg/cm 2), grain size (2.5, 4, 10 μm), and applied coating (no coating, reflectors and absorbers). In addition, a non-uniform layer was introduced to some samples in order to provide an inherent diffusion layer. The experimental results showed that the introduction of a reflector increases the point spread function (PSF) and increases light yield up to 30%, while an absorber reduces the PSF tails and decreases the light yield up to 35%. The PSF linearly increases with thickness, while the greatest light yield was obtained with phosphor samples of 4 μm particle size.