Abstract

Two extreme limits of collisional coupling in termolecular recombination are investigated. The coupled nearest neighbor (CNN) limit includes only couplings between neighboring excited energy levels of the associating species AB*, while the uncoupled intermediate levels (UIL) limit includes only couplings between the fully dissociated reactants A+ and B− and each of the (assumed uncoupled) excited levels of AB*, which are then coupled to the fully associated products AB. Comparison is made with results of previous exact and diffusion treatments.

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