Abstract
On introducing the probabilities for association as a function of internal separation R and internal energy E of the associating (A–B) species the strong collision model is thoroughly investigated and compared, as a case study, with the exact treatment of termolcular ion–ion recombination at low gas densities. A bottleneck model is also investigated. Analytical expressions for the one way equilibrium energy-change rates at fixed R are provided in the Appendix.
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