Abstract
In agreement with the results reported by Lipsky, emission from cyclohexane depends on the temperature T and on the nature of the phase (liquid or solid). Determination of the lifetimes of the fluorescent state with a single photon counting apparatus gives similar results. Our experimental work shows that the rate constant of fluorescence for the solid phase I (face-centered cubic cell) practically does not depend on temperature. Variations of lifetime vs. T cannot easily be interpreted only with the classical theory of non-radiative transitions.
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