Abstract
Enthalpies of dilution of urea (U) solutions in formamide (FA), ethylene glycol (EG) and water were measured calorimetrically in the temperature range between (288.15 and 318.15) K. Based on the results obtained, the enthalpy-homotactic coefficients of pairwise (h22) and triplet (h222) interactions between the solvated U molecules were computed and compared with the similar data for the respective solutions of tetramethylurea (TMU). An analysis was done of how temperature influences the solvophilic and solvophobic effects manifested in the h22 and h222 parameters for U and TMU in the studied organic solvents with a spatial H-bonding network.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
