Temperature dependence of surface microstructure of 316 L stainless steel exposed to low-energy hydrogen ion irradiation

Abstract

The austenitic 316 L stainless steel (316LSS) is an important metal for nuclear installations due to its high strength, good plastic toughness and excellent corrosion resistance, and is commonly used as the plasma-facing and structural material. In this study, 316LSS samples are irradiated with low-energy hydrogen ions (35 eV) at the temperature of 400–1300 K to investigate the surface microstructure evolution. The experimental results show that the surface of 316LSS samples remains relatively smooth at 400 K and 600 K after irradiation. Significant surface roughening including spherical protrusions is formed on the surface at 800 K and 1100 K, and step-like streaks are observed at 1300 K. However, no drastic change in the surface morphology is observed in the separate annealing experiments at 800–1300 K. It has been shown that hydrogen ion irradiation mainly causes the surface microstructure evolution of 316LSS samples. After hydrogen plasma exposure, a large number of adatoms are first formed on the surface of 316LSS because of bubble growth. The adatoms then preferentially reach the defects by diffusion at certain temperatures, and aggregate into spherical protrusions with low surface energy. The qualitative simulation results show that the irradiation temperature affects the diffusion and aggregation of adatoms on the surface, and the radius of the spherical protrusions gradually increases due to the decrease of the surface binding energy and the increase of the irradiation fluence.