Abstract
1. Telomerization of ethylene with acetaldehyde dimethylacetal gives three series of products: acetals CH3CH(OCH3)OCH2(CH2CH2)nH (n=1-3), acetates CH2CO2CH2(CH2CH2)nH (n= 1 and 3), and ketones CH2CO(CH2CH2)nH (n=1-3). 2. To account for the formation of propyl and heptyl acetates a scheme has been proposed which includes the rearrangement of the growing radicals with 1,5- and 1,9- migration of hydrogen, respectively.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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