TC@MF phase change microcapsules with reversibly thermochromic property for temperature response and thermoregulation

Abstract

A series of reversibly thermochromic phase-change microcapsules (TC@MF), demonstrating excellent energy storage and release properties, were synthesized using melamine formaldehyde resin (MF) encapsulated ternary complex consisting of crystal violet lactone (CVL), 2,2-Di-(4-hydroxyphenyl) propane (BPA), and n-hexadecanol. The microstructure, chemical composition, thermal storage capacity, thermal cycling durability, discoloration effect, and thermal regulation performance of TC@MF with different core contents were investigated in detail. With core contents gradually increasing, the chromatic aberration values (ΔE) value of TC@MF increased from 38.23 to 71.69, the melting enthalpy (ΔHm) gradually increased from 180.2 J/g to 218.6 J/g while the leak-proof performance decreased gradually. The TC@MF-2 with the best comprehensive performance has exhibited superior latent heat storage (ΔHm = 192.2 J/g), high chromatic aberration values (ΔE = 57.31), and well leak-proof properties (5.61 %). Furthermore, the thermal performance, morphology, and reversible color reliability of TC@MF-2 remained stable through 100 thermal heating and cooling cycles, demonstrating excellent thermal cycling stability. In summary, such multifunctional microcapsules can directly reflect the energy saturation and depletion states in phase change material applications through color changes. That might be conducive to expanding the value of its practical application in the field of latent heat energy storage, including smart fabrics or fibers, commodity packaging, thermal sensors, reversible thermochromic coatings and solar energy storage, and so on.