Systematic investigation of MAX phase (Ti3AlC2) modified polyethersulfone membrane performance for forward osmosis applications in desalination

Abstract

The current work presented an in-depth investigation of the design and fabrication of thin film membranes for desalination applications by forward osmosis (FO). This includes manipulating the substrate membrane structure aiming to optimize the final thin film composite membrane characteristics. In this context, the MAX phase (Ti3AlC2) as a 2D material has been harnessed to impart novel desirable traits on the prepared membrane. MAX phase has been impregnated in two disparate concentrations and three different scenarios including the substrate membrane and the polyamide layer in both the aqueous and organic phases during the interfacial polymerization. Membranes were comprehensively characterized by a series of experimental tools and methodologies including Atomic Force Microscopy, Scanning Electron Microscopy, Contact Angle, Fourier-transform infrared spectroscopy, pore size and porosity. Results disclosed that substrate membrane structure has a pivotal impact on final TFC/TFN membrane performance. Besides, the MAX phase (Ti3AlC2) could significantly enhance the morphological characteristics of the membrane and ultimately the performance in terms of water flux and reverse salt flux based on the content and the way impregnated. The permeation properties of the composite membranes were significantly superior to the pure PES membrane and the mean pore size also increased with the addition amount of MAX phase (Ti3AlC2) increased.