Abstract

Efforts are made to improve the hardness of rubidium halide crystals by (i) solid solution hardening and (ii) impurity hardening. Systematic microhardness measurements have been made on rubidium halide mixed crystals (RbBr-RbI and KI-RbI) and rubidium halide crystals doped with Sr2+ ions. The composition dependence of the hardness of mixed crystals follows the law ΔH v =K x (1− x),where ΔH v is the enhancement in hardness,K a constant andx and (1 −x) the concentrations of the first and second component of the mixed crystals, respectively. The hardness of doped crystals increases with the concentrationC of the dopant according to the law, ΔH v+6 =k C m,wherek andm are constants. The relative efficacy of the two methods of hardening is discussed.

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