Abstract

A laboratory-scale solid oxide fuel cell (SOFC) system using liquefied natural gas (LNG) as a fuel is designed to be used as an energy converter on seagoing vessels (MultiSchIBZ project). The presented system design phase is supported by thermodynamic system simulation. As heat integration plays a crucial role with regard to fuel recirculation and endothermic pre-reforming, the heat exchanger and pre-reforming component models need to exhibit a high degree of accuracy throughout the entire operating range. Compact additively manufactured tube-bundle and plate-fin heat exchangers are designed to achieve high heat exchange efficiencies at low pressure losses. Their heat transfer correlations are derived from experimental component tests under operating conditions. A simulation study utilizing these heat exchanger characteristics is carried out for four configuration variants of pre-reforming and heat integration. Their system behaviour is analyzed with regard to the degree of pre-reforming and the outlet temperature of the fuel processing module. The combination of allothermal pre-reforming with additively manufactured plate-fin heat exchangers exhibits the best heat integration performance at nominal full load and yields a partial load capability to up to 60% electrical load at net electrical efficiencies of 58 to 60% (LHV).

Highlights

  • The decarbonization of the maritime sector is considered a major step to reduce the anthrophogenic greenhouse gas (GHG) emissions responsible for global warming

  • Ratio of the pre-reforming gas mixture, and the heat capacity rates (Ċ = ṅ · Cp,m ) of both fluids involved in the heat transfer taking place in the allothermal pre-reformer or exhaust gas heat exchanger

  • At larger RR, this behaviour reverses as Ċc > Ċh = Ċmin. This is caused by the increase of the molar flow of the recirculated stream ṅAOG,rec with simultaneous decrease of the exhaust gas flow as less fuel is supplied to the oxidation unit and less air is required to remain at the constant oxidation unit exhaust temperature

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Summary

Introduction

The decarbonization of the maritime sector is considered a major step to reduce the anthrophogenic greenhouse gas (GHG) emissions responsible for global warming. According to the most recent International Maritime Organization (IMO) study, the global shipping sector caused up to 1.056 billion tons of CO2 emissions in the year 2018, contributing to. 2.89% of the global anthropogenic CO2 emissions [1]. The IMO aims to reduce the maritime CO2 emissions by half in 2050 compared to a 2008 reference level [2]. Besides technical and operational improvements (e.g., hydrodynamic ship designs, propulsion efficiency, voyage optimisation, etc.), the use of alternative fuels as well as the implementation of alternative energy converters are considered to be measures with the most significant impact [3]. The spectrum of fuel candidates ranges from lower-carbon fossil fuels like liquefied natural gas (LNG), methanol and biofuels to their synthetically produced counterparts from renewable energies like synthetic natural gas (SNG) to carbon free fuels like hydrogen and ammonia [4,5]

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