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https://doi.org/10.1016/j.tetasy.2010.04.068
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Cite Journal: Tetrahedron: Asymmetry |  Publication Date: Jul 23, 2010 |
 Citations: 11 |
Affiliation: Indian Institute of Chemical Technology
A stereoselective synthesis of the C 8–C 19 segment of cruentarens A and B, cytotoxic natural products, has been accomplished. The key steps involve a stereoselective radical cyclization, stereospecific methylation of a γ, δ-epoxy acrylate, nucleophilic epoxide ring opening and a cis-Wittig olefination.
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