Abstract
The titanium (II) complex, Cp 2Ti(HBcat) 2, catalyzes the hydroboration of diphenylvinylphosphine by catecholborane and pinacolborane to afford exclusive anti-Markovnikov phosphanyl(organyl)boranes cleanly, rapidly and in good yields. Spectroscopic and X-ray studies of the phosphanyl(organyl)borane products show no evidence of boron–phosphorus interaction, indicating that the compounds preclude formation of Lewis pairs.
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