Abstract
A series of hitherto unreported μ-oxy-bis[triphenylantimony(V)]dicarboxylates and μ-oxy-bis[triphenylantimony(V)] chlorocarboxylates of general formula Ph3Sb(L)-O-Sb(L)Ph3 and Ph3Sb(Cl)-O-Sb(L)Ph3, respectively have been synthesized by the metathetical reaction of μ-oxybis-[triphenylantimony(V)]dichloride and silver salts of corresponding carboxylic acids in 1:2 and 1:1 molar ratio [where L = thiosalicyclic acid, p-nitrobenzoic acid, p-aminobenzoic acid, p-fluorobenzoic acid, o-chlorobenzoic acid]. The newly isolated antimony carboxylates have been identified on the basis of melting points, elemental analysis, FT-IR, 1H NMR,13C NMR, 19F NMR. The molecular weight and conductivity data indicate the monomeric and non-electrolytic behaviour in solution. Compounds have been evaluated for their antifungal and antibacterial activity.
Published Version
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