Abstract
AbstractThe doubly‐bridged iron(II)‐tetraphenylporphyrin derivative 6, carrying a sterically fixed S− ligand in the ‘proximal’ position and the substrate at the ‘distal’ site, was synthesised as an enzyme model for cytochrome P‐450. Compound 36, the CO complex of 6, displays a split Soret band (403 and 457 nm) similar to the native cytochrome P‐450.
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