Synthesizing sulfhydryl-functionalized biochar for effectively removing mercury ions from contaminated water.

Abstract

Biochar is regarded as an effective adsorbent for heavy metal pollution treatment, and functional optimization is still needed to improve its performance. We created raw biochar (BC and BP) from corn straw and pine sawdust, which were modified to produce sulfhydryl-modified biochar (MBC and MBP). Isothermal adsorption experiments and adsorption kinetics experiments as well as the related model fitting were performed to evaluate the adsorption performance of biochar on Hg(II). According to the results of the Langmuir model fitting, the maximum adsorption capacities of sulfhydryl-modified biochar were 193.05mg/g (MBC) and 178.04mg/g (MBP), respectively, which were approximately 1.6 times higher than the raw biochar. The results showed that adding sulfhydryl groups to biochar can improve its adsorption performance. The prompt effect resulted from the sulfhydryl modification providing additional functional groups and enhanced chemisorption and physical adsorption properties.