Synthesized CuO-PEI-JE with 3D open-cell structure as an efficient heterogeneous activator of peroxodisulfate for phenol degradation

Abstract

The core of heterogeneous catalytic systems is to design high-performance heterogeneous catalysts. In the present study, CuO-PEI-JE was synthesized via in situ precipitation of CuO on the 3D structure of PEI-JE prepared by a cross-linking method. It possessed a macro-size and 3D open-cell structure, being easily separated and having super-performance for PDS activation. Compared to PDS alone (0.0017 min-1), the CuO-PEI-JE+PDS+NaHCO3 system increased the kobs (0.3526 min-1) by a factor of 207 with 100% phenol degradation within 20 min and 87% TOC removal at 30 min. It outperformed many other published heterogeneous persulfate systems in phenol degradation. Meanwhile, the developed system displayed a good anti-interference ability in the coexistence of anions or different water matrixes. After five successive cycles, the degradation rate still kept 100%, exhibiting the excellent reusability of CuO-PEI-JE. Furthermore, the preparation of CuO-PEI-JE had the advantages with moderate preparation conditions (60 °C) and readily available raw materials. The activation mechanism was mainly involved in the formation of active PDS and its further decomposition into ·OHads, SO4·-ads, O2·- and 1O2. Surface functional groups and phenol acted as electron donors for active PDS. Phenol was first degraded into hexadienedioic acid, then oxidized to propane diacid and oxalic acid, and finally mineralized into CO2 and H2O. This work provides a new strategy for preparing effective heterogeneous persulfate activators and has high potential for the treatment of phenol-containing wastewater.