Abstract

The hyperbranched epoxy resins (HBE) composed of bisphenol A (BPA) and polyethylene glycol (PEG) as reactants and pentaerythritol as branching point were successfully synthesized via A2 + B4 polycondensation reaction at various BPA/PEG ratios. The 13C NMR spectra revealed that the synthesized HBE mainly had a dendritic structure as confirmed by the high degree of branching (DB). The addition of PEG in the resin enhanced degree of branching (DB) (from 0.82 to 0.90), epoxy equivalent weight (EEW) (from 697 g eq−1 to 468 g eq−1) as well as curing reaction. Adding 5–10 wt.% PEG in the resin decreased the onset and peak curing temperatures and glass transition temperature; however, adding 15 wt.% PEG in the resin have increased these thermal properties due to the lowest EEW. The curing kinetics were evaluated by fitting the experimental data of the curing behavior of all resins with the Šesták–Berggren equation. The activation energy increased with the increase of PEG in the resins due to HBE’s steric hindrance, whereas the activation energy of HBE15P decreased due to a large amount of equivalent active epoxy group per mass sample. The curing behavior and thermal properties of obtained hyperbranched BPA/PEG epoxy resin would be suitable for using in electronics application.

Highlights

  • Epoxy thermoset has become the most recognized adhesive and is widely used in demanding industries such as aerospace, automotive, building and construction, and electrical and electronics industries

  • The curing behavior and thermal properties of obtained hyperbranched bisphenol A (BPA)/polyethylene glycol (PEG) epoxy resin would be suitable for using in electronics application

  • The commercial epoxy adhesive is based on diglycidyl ether of bisphenol A (DGEBA) because of high thermal and mechanical properties, good weather and chemical resistances, low shrinkage, and high adhesion strength [1,2,3]

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Summary

Introduction

Epoxy thermoset has become the most recognized adhesive and is widely used in demanding industries such as aerospace, automotive, building and construction, and electrical and electronics industries. For the electrical and electronics industries, especially hard disk drive (HDD) production, thermoset epoxy has been used to adhere the important parts, such as head gimbal assembly (HGA). The physical, thermal, mechanical, thermomechanical, and rheological properties of the thermoset epoxy used in HDD should be investigated in order to match the HGA process in HDD production. The commercial epoxy adhesive is based on diglycidyl ether of bisphenol A (DGEBA) because of high thermal and mechanical properties, good weather and chemical resistances, low shrinkage, and high adhesion strength [1,2,3]. The modification of epoxy by an incorporation of toughening agent and plasticizer was investigated and the natures of these fillers are of great importance affecting the final properties of the cured epoxy-based adhesive products

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