Abstract
The hydrothermal reaction of ZnCl 2 with 5-(4-pyridyl)tetrazole afforded the 2D metal–organic coordination framework [Zn(OH)(4-ptz)] ( 1) and the mononuclear complex [Zn(4-ptz) 2(H 2O) 4]∙2(H 2O) ( 2) [4-ptz = 5-(4-pyridyl)-tetrazolate]. Compound 1 consists of a zig-zag bidimensional network formed by rectangular (4,4) grid sheets. Molecules of 2 form a 3D extended network of hydrogen bonding involving water molecules and the tetrazolate ligand. In addition, compound 1 exhibits strong fluorescence at room temperature in the solid state.
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