Abstract
Abstract The new charge transfer salt (BEDT-TTF)2[N(SO2CF3)2] was synthesized and structually characterized. Its unit cell parameters at 295 K are: a = 6.6394(13) A, b = 8.658(2) A, c = 17.349(4) A, α = 94.70(2)°, β = 97.21(2)°, γ = 68.95(2)°, V = 922.7(4) A3, space group P 1, and Z = 1. The anion, N(SO2CF3)2 −, was found to be disordered, which may relate to the absence of the V4 and V5 Ag modes of the BEDT-TTF molecule in the Raman spectrum. ESR measurements reveal its semiconductive behavior with a small energy gap of 18.7 meV.
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