Synthesis, structure, and spin equilibrium properties of [FeIIIX2L]BPh4⋅solvents (X = 1-methylimidazole and imidazole; L = N, N′-bis(3-ethoxycarbonylsalicylidene)ethylenediamine)

Abstract

Two iron(III) complexes [FeIIIX2L]BPh4⋅solvents (X=1-Meim (1), Him (2)) were synthesized and the crystal structures were determined, where H2L=N, N’-bis(3-ethoxycarbonylsalicylidene)ethylenediamine, 1-Meim=1-methylimidazole, Him=imidazole, BPh4−=tetraphenylborate. FeIII ion has an octahedral coordination environment by N2O2 donor atoms of equatorial L2− and N2 donor atoms of axial imidazoles. Complex 1 is described as isolated molecule, while complex 2 has a hydrogen-bonded cyclic dimer structure constructed by hydrogen-bond between imidazole group and ethoxycarbonyl oxygen via ethanol. Complex 1 is in a high-spin (S=5/2) state over the whole temperature region 5–300K, while complex 2 showed a gradual complete spin equilibrium between high and low-spin states at T1/2=192K.