Abstract

A new 1D Cd(II) complex [Cd(L-pheA)(Ac)]n (1) where the L-pheA– anion stands for the chiral ligand (L-phenylalanine hydroxamic acid) is synthesized and characterized. The single crystal X-ray analysis reveals that each Cd(II) atom is coordinated by three L-pheA– ligands and two acetate anions in a distorted seven-coordinated pentagonal bipyramidal configuration. By the interactions of two N—H⋯O and one N—H⋯N hydrogen bonds a 2D supramolecular network is formed. The solid-state luminescent properties of complex 1 are observed.

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