Abstract

A new mixed‐valence trinuclear manganese(III/II/III) complex was synthesized by ethanolamine and paeonol in the presence of Mn(acetato)2·4H2O. The crystal of the complex was characterized by X‐ray diffraction, IR, UV spectroscopy, molar conductivity and elemental analyses. The structurally characterized mixed‐valence complex has strictly 180° MnIII‐ MnII‐ MnIII angle as required by crystallographic inversion symmetry. The Mn(1) … Mn(2)#1 separation is 3.0500(8) Å. Antimicrobial activity study found that the complex was active against Salmonella species, Staphylococcus aureus, Bacillus pumilus and Eschierichia coli.

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