Abstract
Abstract The first mixed-metal azido bridged complex of Cr(III)–Na(I) has been prepared and its structure is determined. Reaction of chromium(III) chloride and sodium azide with bis-[(E)-N′-(1-(pyridin-2-yl)ethylidene)]carbohydrazide (HL) produced the tetranuclear complex [Cr2Na2(L)2(CH3OH)2(μ-N3)4(N3)2] (1) in good yield. The structure is composed of idealized octahedral [CrIII(N5O)] cores linked to the octahedral [Na(N4O2)] cores by two bridging azide ligands. Magnetic properties and EPR of 1 were also studied.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
