Abstract
In the title compound, [Cd2(C6H4NO3)2(N3)2(H2O)2]n, one CdII atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The other CdII atom, also lying on an inversion center, is coordinated by four O atoms from two bridging 1-oxoisonicotinate ligands and two water molecules and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry. The Cd atoms are connected via the 1-oxoisonicotinate and azide ligands into a two-dimensional coordination network. The crystal structure involves O—H⋯N and O—H⋯O hydrogen bonds.
Highlights
CdII atom is located on an inversion center and is coordinated by four O atoms from four bridging 1-oxoisonicotinate ligands and two N atoms of two bridging azide ligands in a slightly distorted octahedral geometry
Symmetry codes: (viii) −x+1, −y+1, −z+1; (ix) −x+1, −y+1, −z+2
Summary
Engineering, Southeast University, Nanjing 210096, People’s Republic of China, and b
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