Synthesis, spectral and thermal characterization of polyester derived from 1,1-bis(4-hydroxyphenyl)cyclohexane

Abstract

A series of polyesters with pendant cyclohexane ring as a cardo group were synthesized by reacting 1,1-bis(4-hydroxyphenyl)cylcohexane (bisphenol-Z (BPZ)) with diacid chlorides. The molecular structures of the monomer and polymers were confirmed by spectral analyses. Thermal properties were studied using thermogravimetric analysis and differential scanning calorimetry. The thermogravimetric data revealed that the polymers are stable up to 190°C and start to degrade thereafter. The thermal stability initially increases with increase in spacer length and then decreases due to negative effects of the spacer. In the present study, Arrhenius, Broido and Horowitz–Metzger models have been used to calculate the degradation kinetic parameters.