Abstract
In the context of exploring the role of the polar 4′-(dimethylamino)tolan-4-yl group in 3D (single crystals) and 2D [on Au(111)] self-assembly of tetraarylporphyrins, we synthesized and fully characterized a series of meso-substituted trans-porphyrins. A reliable protocol was developed to test the suitability of molecules for intact deposition on surfaces by sublimation in ultra-high vacuum.
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