Synthesis of zeolite‐derived blue nanopigment and its modification for hydrophobic coating on ceramic tile

Abstract

AbstractThis study presents the successful synthesis of a vibrant blue nanopigment derived from the metastable structure of Na‐heulandite zeolite. Employing ion exchange and coprecipitation methods with cobalt and zinc ions, followed by thermal treatment at 1100°C, resulted Co‐willemite and gahnite phases, confirmed by x‐ray diffraction and Rietveld refinement. Optical analyses verified the blue coloration, with cobalt ion transitions evident. CIE L* a* b* colorimetric analysis placed the pigment in the blue region (L* = 49.19, b* = −22, a* = −11). Application to ceramic tiles, followed by sodium dodecyl sulfate (SDS) modification, produced a nearly superhydrophobic surface (contact angle 140°, sliding angle 8°), attributed to the nano–micro structure and SDS–silica interaction. Field emission‐scanning electron microscopy images confirmed the pattern‐like surface with small patterns. These findings indicate potential self‐cleaning capabilities when exposed to dirt or water, highlighting the research's promise in enhancing ceramic functionality.