Synthesis of titanium oxide and titanium nitride nano-particles with narrow size distribution by supersonic thermal plasma expansion

Abstract

The paper reports the synthesis of nano-crystalline ceramics like titanium dioxide and titanium nitride using a plasma chemical experimental reactor powered by a multi-segment (cascaded) arc plasma torch. The precursor-laden plasma beam emerging from the torch anode section expands supersonically through a converging nozzle to a low-pressure collection chamber. This results in a uniform and controlled gas dynamic quenching ensuring rapid synthesis of pure, un-coagulated free-flowing particles with a narrow size distribution. Simple Langmuir probes and calorimetric energy balance methods are used for plasma and reactor characterization, while X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic light scattering (DLS), Raman and X-ray photoelectron spectroscopy (XPS) techniques have been used for product analysis. It is shown that size distribution of both the product particles is comparatively narrower than that found in most thermal plasma assisted laboratory synthesis studies. The expansion process was observed to produce a non-equilibrium electron population, which could charge up the particles after nucleation and hence could curb unwanted coagulation.