Synthesis of thin and compact mesoporous MCM-48 membrane on vacuum-coated α-Al 2O 3 tube

Abstract

A thin and compact mesoporous MCM-48 membrane had been successfully synthesized on vacuum-coated α-Al 2O 3 support with pore size of 1 μm. The pretreated supports and the membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and single gas permeation test. The pretreated supports were gas permeable for N 2 and the as-synthesis membrane was gas tight, indicating that the defects left in the vacuum step disappeared in the multi-hydrothermal synthesis process. The XRD pattern of the membrane was represented to the typical cubic I a 3 ¯ d space group. And the SEM images showed that the membrane was continuous and 4-μm thick. Additionally, the separation factor of the calcined membrane for H 2/N 2 was up to 3.33 and the Knudsen contribution to the total flux for N 2 permeation was 97.8%. All the results indicated that the good surface conditions of the large-pore supports improved by the vacuum coating method were favorable for the formation of a compact MCM-48 membrane on it.