Abstract
AbstractSumanene derivatives fused by quinones and acenes were synthesized through Friedel‐Crafts double acylation, followed by reductive aromatization. Single‐crystal X‐ray diffraction analysis on synthesized quinone and acene derivatives revealed the one‐dimensional (1D) columnar stackings predominated by the concave‐convex alignment from sumanene moiety. The thus‐prepared sumanene‐fused acenes exhibited higher solubility to organic solvent and significant stability against aerobic oxidation than the pristine acenes.
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