Abstract
1. Benzoyl peroxide adds rapidly and quantitatively to ethyl vinyl sulfide with formation of ethylthioethylene dibenzoate; this explains why benzoyl peroxide cannot be used as an initiator for the polymerization of vinyl sulfides. 2. Di-tert-butyl peroxide promotes the polymerization of ethyl vinyl sulfide with formation of a polymer of low molecular weight, but it does not give addition products with this vinyl sulfide.
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